Oxygen Effects on Performance of Electrically Bistable Devices Based on Hybrid Silver Sulfide Poly(N-vinylcarbazole) Nanocomposites.
نویسندگان
چکیده
An organic/inorganic bistable device is fabricated by using a simple spin-coating technique, in which the hybrid silver sulfide (Ag2S) poly(N-vinylcarbazole) (PVK) nanocomposite film is sandwiched between two electrodes. An obvious electrical hysteresis is observed in the current-voltage (I-V) curve of the device measured in the presence of different oxygen concentrations, and the magnitude of the electrical hysteresis is decreased with a decrease of the oxygen concentrations. The electrical bistability of the device exhibits a strong dependence on the oxygen concentrations, and the current variation of the OFF state is higher than that of the ON state with the gas atmosphere changing from N2 to air. Different theoretical models have been employed to describe the carrier transport mechanisms of the device in the OFF and ON states measured in different gas atmospheres on the basis of the experimental I-V results, and the carrier transport of the device in the ON state measured in air is very different from that measured in N2 and low O2 concentrations due to the participation of oxygen vacancies in the trapping and de-trapping processes of electrons into and out of the Ag2S/PVK heterointerface.
منابع مشابه
Negative differential resistance and carrier transport of electrically bistable devices based on poly(N-vinylcarbazole)-silver sulfide composites
An electrically bistable device has been fabricated based on poly(N-vinylcarbazole) (PVK)-silver sulfide (Ag2S) composite films using a simple spin-coating method. Current-voltage (I-V) characteristics of the as-fabricated devices exhibit a typical electrical bistability and negative differential resistance (NDR) effect. The NDR effect can be tuned by varying the positive charging voltage and t...
متن کاملN-Vinylcarbazole: As an Additive for Thermal Polymerization at Room Temperature with in situ Formation of Ag(0) Nanoparticules
N-vinylcarbazole (NVK) is proposed as an additive for acrylates thermal free radical polymerization (FRP) and epoxy thermal ring opening polymerization (ROP) at room temperature. The new initiating systems are based on a silane/silver salt/N-vinylcarbazole interaction, which ensures good to excellent polymerization. Moreover, the polymerization is much more efficient under air than under argon....
متن کاملEffects of protective agents (PVA & PVP) on the formation of silver nanoparticles
In this study silver/poly vinyl alcohol (PVA) and silver/poly vinyl pyrrolidone (PVP) Nanocomposites were prepared via reduction of silver salt by employing DMF (N, N`- dimethyl formamide) as a reducing agent. Effects of protective agents such as PVA and PVP were also described here. We show that the acidic pH of PVP solution also affects the interaction between protective agents and silver nan...
متن کاملIn situ synthesis and optical limiting response of poly(N-vinylcarbazole) functionalized single-walled carbon nanotubes.
A new poly(N-vinylcarbazole)-covalently grafted single-wall carbon nanotube (SWNT-PVK) hybrid material was synthesized by an in situ anionic polymerization reaction of N-vinylcarbazole and the negatively charged SWNTs. Incorporation of the PVK moieties onto the SWNTs' surface considerably improves the solubility and processability of SWNTs. At the same level of linear transmission, the SWNT-PVK...
متن کاملElectrical memory devices based on inorganic/organic nanocomposites
Nonvolatile memory devices based on hybrid inorganic/organic nanocomposites have emerged as excellent candidates for promising applications in next-generation electronic and optoelectronic devices. Among the various types of nonvolatile memory devices, organic bistable devices fabricated utilizing hybrid organic/inorganic nanocomposites have currently been receiving broad attention because of t...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Nanoscale research letters
دوره 11 1 شماره
صفحات -
تاریخ انتشار 2016